专利摘要:
Disclosed are compositions comprising a) an antimicrobial agent, which is selected from the group consisting of lactic acids, comprising L(+) optical isomer of lactic acid or a racemic lactic acid, and b) a polyamine, especially a polyethylenimine. The polyamine is effective as a booster for the antimicrobial properties of lactic acid isomers and their mixtures. Compositions can further comprise c) a tensid, and d) a primer for tensid, resulting in better distribution of tensid in the bulk composition, a synergetic effect of b), c) and d) on the biocidal properties of a) is achieved, allowing for a long-term synergetic biocidal effect of our eco-friendly solution at very low biocide concentration. The uses of the disclosed compositions for manufacturing of various biocidal formulations and as various biocidal formulations are claimed.
公开号:DK201800907A1
申请号:DKP201800907
申请日:2018-11-23
公开日:2020-02-27
发明作者:Schmidt Hansen Lars;James Lüscher Christopher;Wagner Daria
申请人:ACT.Global A/S;
IPC主号:
专利说明:

TECHNICAL FIELD
The present invention relates to antimicrobial compositions comprising an L-lactic acid isomer or racemic lactic acid as a biocide in combination with a polyamine. The effect of polyamine as a booster for biocidal properties of said biocide can be further improved by a tensid and a stabilising agent (primer) for the tensid.
BACKGROUND
WO13124784 Al by PURSCHWITZ et al. discloses composition comprising a) an antimicrobial agent, which is selected from the group consisting of biocides containing halogen atoms and/or containing phenolic moieties, formic acid, chlorine dioxide, chlorine dioxide generating compounds, dialdehydes; components containing an antimicrobial metal such as antimicrobial silver, and b) a polyamine, especially a polyethylenimine. The polyamine is effective as a booster for the antimicrobial agent. Though lactic acid and its salts is mentioned in description part of WO13124784 in a big bulk group of possible biocides, and also listed under further additives, improving the antimicrobial effect of the biocide, and even as an antioxidant example later on, there is no mentioning in WO13124784, that especially one of the two optical isomers or a racemic lactic acid would perform better than the other isomer, and lactic acid is not claimed as a biocide, either.Our selection invention discloses that by using the specific isomer of lactic acid or a racemic lactic acid as a biocide, a long-lasting and eco-friendly protective effect can be achieved using much lower concentration of biocide than claimed by WO13124784. The use of a surfactant is disclosed by WO13124784. However, we disclose that by using a tensid for stabilising polyamine, and by using a further additive (a tensid primer) ensuring a better distribution of the tensid in the composition, a surprising synergetic effect is achieved, boosting the biocidal properties of our specifically selected biocide.
Other examples of polyamines for boosting biocideing properties, suitable for our inventive compositions, can be these disclosed by SCHONEMYR et al in US2007042198, US2008286225 and IN04627DN2007, all disclosing polyamines, having polyethyleneamine precursors with various structural and functional modifications.
SUMMARY
In a first aspect, a composition is claimed, comprising a specifically selected biocide a) being L-lactic acid isomer or racemic lactic acid, in amount of up to lwt.% of total weight of the
DK 2018 00907 A1 composition, and a polyamine compound b) in amount of up to 0.1wt.% of total weight of the composition, providing a long-lasting biocidal effect at environment-friendly concentrations.
In a second aspect, the biocidal effect can be further enhanced and prolonged by using a tensid and a primer, where tensid stabilises the polyamine compound, and said primer ensures an even distribution of the tensid in the composition. The use of a polyamine compound b), a tensid c) and a primer d), individually or in any combination for promoting the antimicrobial effect of our selected biocide a), being an L-lactic acid isomer or racemic lactic acid, is claimed. The collective use of a polyamine compound b), a tensid c) and a primer d) provides a synergetic enhancing of biocidal properties of our specific biocide a), allowing for a reduction of the biocide concentration needed for satisfactory disinfection levels.
In a third aspect of the invention, the use of the compositions according to the first aspect of invention for manufacturing of various products is claimed, such as, for the manufacture of home care formulation, such as a biocide, disinfectant, all purpose cleaner, laundry detergent, dishwashing liquid, deodorant, fabric conditioner, product for disinfection and sanitization of hard surfaces, floor cleaner, glass cleaner, kitchen cleaner, bath cleaner, sanitary cleaner, hygiene rinse product for fabrics, carpet cleaner, furniture cleaner, or a product for conditioning, sealing, caring or treating hard and soft surfaces; or for the manufacture of a personal care formulation, especially a deodorant, skin care preparation, bath preparation, cosmetic care preparation, foot-care preparation, light-protective preparation, skin-tanning preparation, depigmenting preparation, insect-repellent, antiperspirant, preparation for cleansing and caring for blemished skin, hair-removal preparation, shaving preparation, fragrance preparation, cosmetic hair-treatment preparation, antidandruff preparation, oral care composition.
In a forth aspect of the invention, the use of the compositions according to the first aspect of invention as various products is claimed, such as home care formulation, such as a biocide, disinfectant, all purpose cleaner, laundry detergent, dishwashing liquid, deodorant, fabric conditioner, product for disinfection and sanitization of hard surfaces, floor cleaner, glass cleaner, kitchen cleaner, bath cleaner, sanitary cleaner, hygiene rinse product for fabrics, carpet cleaner, furniture cleaner, or a product for conditioning, sealing, caring or treating hard and soft surfaces; or for the manufacture of a personal care formulation, especially a deodorant, skin care preparation, bath preparation, cosmetic care preparation, foot-care preparation, light-protective preparation, skin-tanning preparation, depigmenting preparation, insect-repellent, anti- perspirant, preparation for cleansing and caring for blemished skin, hair-removal preparation, shaving preparation, fragrance preparation, cosmetic hair-treatment preparation, antidandruff preparation, oral care composition.
DK 2018 00907 A1
DETAILED DISCLOSURE
In one aspect, a composition comprising of a biocide a) being L-lactic acid isomer or racemic lactic acid and b) being a polyamine is selected from polyethyleneimines of molecular weight higher than 400 g/mol, and preferably has a number-average molecular weight in the range from 500 to 2 000 000 g/mol, especially 750 g/mol to 100 000 g/mol, said polyamine is a homopolymer, or an oligomer or polymer grafted with 0.01 to 100 parts by weight of ethylene oxide on 1 part by weight of the polyamine, most preferably, the polyamine is a branched polyethylenimine homopolymer, whose uncharged form conforms to the empirical formula -(CH2-CH2-NH)n- wherein n ranges from approximately 10 to 100000, or is a grafted variant thereof, shows very good performance. A test based on the European standardized test for Chemical disinfectants and antiseptics was conducted, namely, Quantitaive suspension test for the evaluation of bactericidal activity in the medical area- (DS/EN 13727:2012+A2:2015). In this test, 8ml of solution is taken and mixed with a premix of 1ml of test organisms and 1 ml of interfering solution. After addidtion, the mixture was shortly mixed on a vortex mixer and is left until the contact time being tested has passed. After contact time, 1 ml of the mixture is transferred to a solution comprising 8 ml neutralizer and 1 ml of water, and vortexed again. After 5 mins of neutralization, samples are taken from the mixture and diluted to 10-5 and 10-6 and added to a petri dish (size 90-100 mm). These petri dishes are incubated for 20-24 hours at 36-37 degrees Celsius, and the colony forming units are counted, afterwards, the plates are incubated for another 20-24 hours, and the colony forming units are recounted. If the number of colonies has increased, the higher number will be used.
Our tests showed that the compositions comprising a) and b) especially being the two PEI products A-200 by Appeartex AB and Lupasol FG by BASF, showed up to full reduction (100wt.%) of test organisms at concentrations of a) below 1wt.% and a contact time of 1 min. The compound a) alone showed a lower efficacy of log1.3 (96.55wt.% reduction) at a concentration of 1wt.% and a contact time of 1 min. At a contact time of 5 min the mixture of a) and b) specifically A-200 by Appeartex AB showed a log7 or higher reduction at dilutions of 1:10 of the original test. Compound a) alone at 3wt.% concentration and a contact time of 5 mins achieved a log7 or higher reduction, but only without dilution.
The interaction of a) and b) is considered to give a synergetic effect that amplifies to biocidal activity of a). Compound b) is a cationic polymere and affects the composition by being an attachment promoter, first of this means that a) will lay close and attach with b). Further, because of the attachment promotion the outer surfaces of cells will attract to b) and therefore b) will facilitate strong attachment to microorganisms, allowing a) to effectively kill them.
In second aspect, compound c) stabilises the formulation of a) and b) and upholds a uniform distribution of a) and b). It further lowers the surface tension of the composition, allowing for
DK 2018 00907 A1 a higher contact area between a), b) and the surfaces. Compound d) gives a synergetic effect with c) which leads to an improved product it has a positive effect on the rheology of c) in the composition which leads to an even better distribution in the composition. Further, d) leads to a dermatological improvement of the composition and has a positive effect on the foam building of c). When the composition is applied to a surface, an even distribution of a) and b) through c) and d) assures that a) and b) is distributed evenly over the whole surface and doesn't accumulate in clusters. Compound b) binds a) to the target surface and allows for the release of a) when needed. When applied to a surface, b) creates a strong bond to almost any type of surface, even surfaces that are normally difficult to adhere to, including certain plastic types or inorganic materials, such as glass and tiles. The strong bond makes the product stick to the surface, even when the surface is subjected to a mechanical stress, e.g. rinsing with water. A range of test where done where the composition solutions was applied to a stainless stell surface and left for a set amount of time between 3 hours and 14 days. After the set time has passed, a known amount of test organisms was pipetted onto the surface and left there for the set contact time. After the contact time, the stainless stell plates where added to a neutralizer, in a tube with glass beeds, and the mixture was vortexed to let the glass beeds release the test organisms from the surface. After 5 mins of neutralization, samples where taken and diluted (to concentration of 10-3 and 10-4), and added to a petri dish (size 90-100mm) and incubated for 20-24 hours at 36-37 degrees Celcius. After incubation, the petri dish was counted for colony forming units. The plates are further incubated for another 20-24 hours, and the colony forming units are recounted. If the number of colonies has increased, the higher number is used.
The composition comprising a), b), c) and d) applied to a surface, showed efficacy even 14 days after application. The compound a) alone showed no long-term efficacy, as after 3 days, there was no detectable biocidal effect on a surface where a) was applied alone, at out test concentration.
In a third aspect of the invention, the use of the compositions according to the first aspect of invention for manufacturing of various products is claimed, such as, for the manufacture of industrial, hotel, sport, food, beverage, pool, transportation vehicle, educational area and home care formulation, such as a biocidal composition for cleaning industrial production facilities (cooling, refrigerating and freezing devices, equipment for food processing and beverage production, etc.), or as an antifouling composition and care formulations, such as a biocidal compositions, antifouing compositions, disinfectant, all purpose cleaner, laundry detergent, dishwashing liquid, deodorant, fabric conditioner, product for disinfection and sanitization of hard surfaces, floor cleaner, glass cleaner, kitchen cleaner, bath cleaner, sanitary cleaner, hygiene rinse product for fabrics, carpet cleaner, furniture cleaner, or a product for conditioning, sealing, caring or treating hard and soft surfaces; or for the
DK 2018 00907 A1 manufacture of a personal care formulation, especially a deodorant, skin care preparation, bath preparation, cosmetic care preparation, foot-care preparation, light-protective preparation, skin-tanning preparation, depigmenting preparation, insect-repellent, antiperspirant, preparation for cleansing and caring for blemished skin, hair-removal preparation, shaving preparation, fragrance preparation, cosmetic hair-treatment preparation, antidandruff preparation, oral care composition.
In a forth aspect of the invention, the use of the compositions according to the first aspect of invention as various products is claimed, such as industrial, hotel, sport, food, beverage, pool, transportation vehicle, educational area and home care formulation, such as a biocidal composition for cleaning industrial production facilities (cooling, refrigerating and freezing devices, equipment for food processing and beverage production, etc.), or as an antifouling composition, disinfectant, all purpose cleaner, laundry detergent, dishwashing liquid, deodorant, fabric conditioner, product for disinfection and sanitization of hard surfaces, floor cleaner, glass cleaner, kitchen cleaner, bath cleaner, sanitary cleaner, hygiene rinse product for fabrics, carpet cleaner, furniture cleaner, or a product for conditioning, sealing, caring or treating hard and soft surfaces; or for the manufacture of a personal care formulation, especially a deodorant, skin care preparation, bath preparation, cosmetic care preparation, foot-care preparation, light-protective preparation, skin-tanning preparation, depigmenting preparation, insect-repellent, anti- perspirant, preparation for cleansing and caring for blemished skin, hair-removal preparation, shaving preparation, fragrance preparation, cosmetic hair-treatment preparation, antidandruff preparation, oral care composition.
Specific embodiments of the invention
The invention has been described with reference to a number of embodiments and aspects. However, the person skilled in the art may amend such embodiments and aspects while remaining within the scope of the appended patent claims. Our claimed biocide is Lactic Acid at concentrations of 0.1-1wt.%, in the form of the L-lactic acid isomer, for example from the product series Purac by Corbion, or 80wt.% L(+)-Lactic Acid by Merck or L(+)-Lactic Acid by Jungbunzlauer, or the racemic lactic acid, DL-Lactic acid, for example from the product series Purac by Corbion or 85wt.% DL-Lactic Acid by Merck or DL-Lactic Acid by Wilke International Inc.
The polyamine is from the group of polyethyleneimines of molecular weight higher than 400 g/mol, and preferably has a number-average molecular weight in the range from 500 to 2 000 000 g/mol, especially 750 g/mol to 100 000 g/mol, said polyamine is a homopolymer, or an oligomer or polymer grafted with 0.01 to 100 parts by weight of ethylene oxide on 1 part by weight of the polyamine, most preferably, the polyamine is a branched polyethylenimine homopolymer, whose uncharged form conforms to the empirical formula -(CH2-CH2-NH)n
DK 2018 00907 A1 wherein n ranges from approximately 10 to 100000, or is a grafted variant thereof, for example, PEI from the Lupasol group of products by BASF, or from the polyethylenemine group of products form Merck, or the modyfied PEI by Appeartex AB.
The tensid (compound c) is chosen from the group of non-ionic tensides, produced using an environment-friendly production, for example, Plantacare product line.
The primer is a Cocamidopropyl Betaine, chosen from the Dehyton group by BASF.
Some specific novel and inventive formulations in this scope that have proven efficacy are disclosed in the following embodyments:
EMBODIMENT 1
Compositions comprising 0.1-1 wt.% of a) L(+)-Lactic Acid; 0.0001-0.2wt.% of b) modified PEI (for example, A-200 by Appeartex AB); 0.1-5wt.% of c) D-Glucopyranose, oligomers, decyl octyl glycosides(for example, Plantacare 810UP by BASF) and 0.01-1wt.% of d) Cocamidopropyl Betaine (for example, Dehyton PK45 by BASF).
EMBODIMENT 2
Compositions comprising 0.1-1 wt.% of a) DL-Lactic Acid; 0.0001-0.2wt.% of b) modified PEI (for example, A-200 by Appeartex AB); 0.1-5wt.% of c) D-Glucopyranose, oligomers, decyl octyl glycosides (for example, Plantacare 810UP by BASF) and 0.01-1wt.% of d) Cocamidopropyl Betaine (for example, Dehyton PK45 by BASF).
EMBODIMENT 3
Compositions comprising 0.1-1 wt.% of a) L(+)-Lactic Acid; 0.0001-0.2wt.% of b) modified PEI (for example, A-200 by Appeartex AB); and 0.1-5wt.% of c) D-Glucopyranose, oligomers, decyl octyl glycosides (for example, Plantacare 810UP by BASF).
EMBODIMENT 4
Compositions comprising 0.1-1 wt.% of biocide a) DL-Lactic Acid (for example, Purac by Corbion); 0.0001-0.2wt.% of b) modified PEI (for example, A-200 by Appeartex AB) and 0.15wt.% of c) D-Glucopyranose, oligomers, decyl octyl glycosides (for example, Plantacare 810UP by BASF).
DK 2018 00907 A1
EMBODIMENT 5
Compositions comprising 0.1-1 wt.% of a) DL-Lactic Acid (for example, by Corbion); 0.00010.5wt.% of b) PEI (for example, Lupasol FG by BASF); and 0.1-5wt.% of c) D-Glucopyranose, oligomers, decyl octyl glycosides (for example, Plantacare 810UP by BASF).
EMBODIMENT 6
Compositions comprising 0.1-1 wt.% of a) L(+)-Lactic Acid; 0.0001-0.5wt.% of b) PEI (Lupasol FG by BASF); and 0.1-5wt.% of c) D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF).
EXAMPLE 1
A composition comprising 0.9wt.% L(+)-Lactic Acid (Purac from Corbion), 0.1wt.% modified PEI (A-200 by Appeartex AB), 0.9wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF) and 0.1wt.% Cocamidopropyl Betaine (Dehyton PK45 by BASF).
EXAMPLE 2
A composition comprising 0.9wt.% L(+)-Lactic Acid (by Merck), 0.1wt.% modified PEI (A-200 by Appeartex AB), 0.9wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF) and 0.1wt.% Cocamidopropyl Betaine (Dehyton PK45 by BASF).
EXAMPLE 3
A composition comprising 0.9wt.% DL-Lactic Acid (by Corbion), 0.1wt.% modified PEI (A-200 by Appeartex AB), 0.9wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF) and 0.1wt.% Cocamidopropyl Betaine (Dehyton PK45 by BASF).
EXAMPLE 4
A composition comprising 0.9wt.% DL-Lactic Acid (by Merck), 0,1wt.% modified PEI (A-200 by Appeartex AB), 0.9wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF) and 0.1wt.% Cocamidopropyl Betaine (Dehyton PK45 by BASF).
EXAMPLE 5
A composition comprising 0.9wt.% L(+)-Lactic Acid (Purac by Corbion), 0.1wt.% modified PEI (A-200 by Appeartex AB) and 1wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF).
DK 2018 00907 A1
EXAMPLE 6
A composition comprising 0.9wt.% L(+)-Lactic Acid (by Merck), 0.1wt.% modified PEI (A-200 by Appeartex AB) and 1wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF).
EXAMPLE 7
A composition comprising 0.9 wt.% DL-Lactic Acid (by Corbion), 0.1wt.% modified PEI (A200 by Appeartex AB) and 1wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF).
EXAMPLE 8
A composition comprising 0.9 wt.% DL-Lactic Acid (by Merck), 0.1wt.% modified PEI (A-200 by Appeartex AB) and 1wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF).
EXAMPLE 9
A composition comprising 0.9wt.% L(+)-Lactic Acid (Purac from Corbion), 0.25wt.% PEI (Lupasol FG by BASF), 0.9wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF) and 0.1wt.% Cocamidopropyl Betaine (Dehyton PK45 by BASF).
EXAMPLE 10
A composition comprising 0.9wt.% L(+)-Lactic Acid (by Merck), 0.25wt.% PEI (Lupasol FG by BASF), 0.9wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF) and 0.1wt.% Cocamidopropyl Betaine (Dehyton PK45 by BASF).
EXAMPLE 11
A composition comprising 0.9wt.% DL-Lactic Acid (by Corbion), 0.25wt.% PEI (Lupasol FG by BASF), 0.9wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF) and 0.1wt.% Cocamidopropyl Betaine (Dehyton PK45 by BASF).
EXAMPLE 12
A composition comprising 0.9wt.% DL-Lactic Acid (by Merck), 0.25wt.% PEI (Lupasol FG by BASF), 0.9wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF) and 0.1wt.% Cocamidopropyl Betaine (Dehyton PK45 by BASF).
DK 2018 00907 A1
EXAMPLE 13
A composition comprising 0.9wt.% L(+)-Lactic Acid (Purac by Corbion), 0.25wt.% PEI (Lupasol FG by BASF) and 1wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF).
EXAMPLE 14
A composition comprising 0.9wt.% L(+)-Lactic Acid (by Merck), 0.25wt.% PEI (Lupasol FG by BASF) and 1wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF).
EXAMPLE 15
A composition comprising 0.9 wt.% DL-Lactic Acid (by Corbion), 0.25wt.% PEI (Lupasol FG by BASF) and 1wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by BASF).
EXAMPLE 16
A composition comprising 0.9 wt.% DL-Lactic Acid (by Merck), 0.25wt.% PEI (Lupasol FG by
BASF) and 1wt.% D-Glucopyranose, oligomers, decyl octyl glycosides (Plantacare 810UP by
权利要求:
Claims (10)
[1] 1. Composition comprising a) an antimicrobial agent selected from the group consisting of L(+)-lactic acid (this isomer is also called (S)-lactic acid) and racemic lactic acid (also called DL-lactic acid, comprising a mixture of the two optical isomers in equal amounts), and b) a polymer binder selected from polyamines, especially polyethylenimines.
[2] 2. Composition of claim 1, wherein the polyamine is selected from polyethyleneimines of molecular weight higher than 400 g/mol, and preferably has a number-average molecular weight in the range from 500 to 2 000 000 g/mol, especially 750 g/mol to 100 000 g/mol, said polyamine is a homopolymer, or an oligomer or polymer grafted with 0.01 to 100 parts by weight of ethylene oxide on 1 part by weight of the polyamine, most preferably, the polyamine is a branched polyethylenimine homopolymer, whose uncharged form conforms to the empirical formula -(CH2-CH2-NH)n- wherein n ranges from approximately 10 to 100000, or is a grafted variant thereof.
[3] 3. Composition according to any of claims 1 to 2, which composition contains 0.001 to 1 percent b.w. of the biocide (a), relative to the total weight of the composition.
[4] 4. Composition according to any of claims 1 to 3, which composition contains 0.001 to 1 percent b.w. of the polyamine (b), preferably, 0.001 to 0.5 percent b.w., most preferably, 0.1 percent b.w. of the polyamine compound b) relative to the total weight of the composition.
[5] 5. Composition according to any of claims 1 to 4, comprising at least one further com- ponent (c) selected from the group consisting of tensids, surface active agents, hydrotropic agents, further additives that may improve the antimicrobial effect, and stabilising biocide (a) and/or polyamine, especially selected from surfactants such as the group consisting of tensids, anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants; preferably, component (c) is comprising Cocoglycoside.
[6] 6. Composition according to claim 5, which composition contains 0.001 to 1 percent b.w. of a surfactant (c), relative to the total weight of the composition.
[7] 7. Composition according to claim 5 or 6, comprising at least one further component (d) for stabilising and more evenly distribulting component (c), the component (d) being a fatty acid amide derivative with Betaine Structure, most preferably, Cocamidopropyl Betaine.
[8] 8. Use any of components (b), (c) and (d) as described in related corresponding claims 1 -7 as a booster for a biocide (a) for a synergetic effect.
[9] 9. Use of a composition according to any of claims 1 to 7 for the manufacture of industrial, hotel, sport, food, beverage, pool, transportation vehicle, educational area and home care
DK 2018 00907 A1 formulation, such as a biocidal composition for cleaning industrial production facilities (cooling, refrigerating and freezing devices, equipment for food processing and beverage production, etc.), or as an antifouling composition, care formulation, such as a biocide, disinfectant, all purpose cleaner, laundry detergent, dishwashing liquid, deodorant, fabric conditioner, product for disinfection and sanitization of hard surfaces, floor cleaner, glass cleaner, kitchen cleaner, bath cleaner, sanitary cleaner, hygiene rinse product for fabrics, carpet cleaner, furniture cleaner, or a product for conditioning, sealing, caring or treating hard and soft surfaces; or for the manufacture of a personal care formulation, especially a deodorant, skin care preparation, bath preparation, cosmetic care preparation, foot-care preparation, light-protective preparation, skin-tanning preparation, depigmenting preparation, insect-repellent, anti- perspirant, preparation for cleansing and caring for blemished skin, hair-removal preparation, shaving preparation, fragrance preparation, cosmetic hair-treatment preparation, antidandruff preparation, oral care composition.
[10] 10. Use of a composition according to any of claims 1 to 7 as an industrial, hotel, sport, food, beverage, pool, transportation vehicle, educational area and home care formulation, such as a biocidal composition for cleaning industrial production facilities (cooling, refrigerating and freezing devices, equipment for food processing and beverage production, etc.), or as an antifouling composition, care formulation, such as a biocide, disinfectant, all purpose cleaner, laundry detergent, dishwashing liquid, deodorant, fabric conditioner, product for disinfection and sanitization of hard surfaces, floor cleaner, glass cleaner, kitchen cleaner, bath cleaner, sanitary cleaner, hygiene rinse product for fabrics, carpet cleaner, furniture cleaner, or a product for conditioning, sealing, caring or treating hard and soft surfaces; or as a personal care formulation, especially a deodorant, skin care preparation, bath preparation, cosmetic care preparation, foot-care preparation, light-protective preparation, skin-tanning preparation, depigmenting preparation, insect-repellent, antiperspirant, preparation for cleansing and caring for blemished skin, hair-removal preparation, shaving preparation, fragrance preparation, cosmetic hair-treatment preparation, antidandruff preparation, oral care composition.
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同族专利:
公开号 | 公开日
WO2020103997A1|2020-05-28|
DK180059B1|2020-02-27|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题

DE1816348A1|1968-12-21|1970-06-25|Henkel & Cie Gmbh|Washing, bleaching and cleaning agents|
US6455058B1|2000-09-13|2002-09-24|Amitee Cosmetics, Inc.|Composition and method for hair and scalp treatment|
CN104245781B|2012-02-20|2018-09-21|巴斯夫欧洲公司|The antimicrobial acivity of biocide is improved with polymer|
US20140170237A1|2012-12-14|2014-06-19|Yueh Wang|Antimicrobial compositions containing mixtures of fatty and hydroxyl carboxylic acids|
FI128215B|2013-05-28|2019-12-31|Argenlab Global Ltd|Low alcohol content disinfection foams|
EP3094757B1|2014-01-16|2019-06-19|Uddeholms AB|Stainless steel and a cutting tool body made of the stainless steel|
US11033023B2|2014-11-26|2021-06-15|Microban Products Company|Surface disinfectant with residual biocidal property|
法律状态:
2020-02-27| PAT| Application published|Effective date: 20200227 |
2020-02-27| PME| Patent granted|Effective date: 20200227 |
优先权:
申请号 | 申请日 | 专利标题
DKPA201800907A|DK180059B1|2018-11-23|2018-11-23|Eco-friendly long-term protection compositions and uses|DKPA201800907A| DK180059B1|2018-11-23|2018-11-23|Eco-friendly long-term protection compositions and uses|
PCT/DK2019/050364| WO2020103997A1|2018-11-23|2019-11-22|Eco-friendly long-term protection compositions and uses|
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